ELECTROCHEMICAL SYNTHESIS OF N-OXOPYRIDINE-2-THIONATE COMPLEXES OF CD(II) - THE CRYSTAL-STRUCTURE OF BIS(2,2'-BIPYRIDINE)(N-OXOPYRIDINE-2-THIONATE) CADMIUM(II) PERCHLORATE-1 4(BIPYRIDINE)/

Authors
SANMARTIN J BERMEJO MR ROMERO J GARCIAVAQUEZ JA SOUSA A BRODBECK A CASTINEIRAS A HILLER W STRAHLE J
Citation
J. Sanmartin et al., ELECTROCHEMICAL SYNTHESIS OF N-OXOPYRIDINE-2-THIONATE COMPLEXES OF CD(II) - THE CRYSTAL-STRUCTURE OF BIS(2,2'-BIPYRIDINE)(N-OXOPYRIDINE-2-THIONATE) CADMIUM(II) PERCHLORATE-1 4(BIPYRIDINE)/, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(4), 1993, pp. 431-437
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
4
Year of publication
1993
Pages
431 - 437
Database
ISI
SICI code
0932-0776(1993)48:4<431:ESONCO>2.0.ZU;2-6
Abstract
The electrochemical oxidation of Cd in acetonitrile solution of 1-hydr oxy-2-pyridinethione (HPT) and 2,2'-bipyridine (bipy) affords [Cd(PT)2 (bipy)] . H2O and [Cd(PT)(bipy)]ClO4 . 1/4(bipy). The crystal structur e of the perchlorate salt shows the molecule to have a distorted octah edral CdN4OS skeleton.