Internal friction peaks measured as a function of temperature or frequ
ency have been associated to non-linear processes only after studying
how the amplitude of the applied stress affects the relaxation process
. Here it is demonstrated that the partial derivative of the internal
friction with respect to the frequency at constant temperature is a us
eful tool to determine that non-linear effects are involved. This anal
ysis applied to actual data of the Snoek relaxation in Nb-O, reveals t
hat at high interstitial contents non-linear effects appear.