The chemical and electronic aspects of a Ga-As (100) surface passivate
d by selenium sulfide (SeS2) have been investigated by x-ray photoelec
tron spectroscopy and photoluminescence. It has been observed that thi
s treatment gives rise to an arsenic selenide (As2Se3) terminated surf
ace. No S-GaAs bonds were observed. The remarkable electronic properti
es and the formation of the chemically and thermally stable As2Se3 pha
se reveals the successful passivation. Passivation of GaAs in single s
tep and identification of a single selenium species on the surface are
considered to be the major advantages of using SeS2.