T. Ikari et al., PHOTOACOUSTIC INVESTIGATIONS OF SHALLOW ACCEPTORS IN SILICON BY A PIEZOELECTRIC TRANSDUCER, IEEE transactions on ultrasonics, ferroelectrics, and frequency control, 40(2), 1993, pp. 110-113
Photoacoustic (PA) measurements of p-Si single crystals near an optica
l absorption edge were carried out by using a PZT as a detector. A pro
nounced peak at 1.07 eV appears in addition to the plateau above 1.2 e
V. A hole carrier concentration dependence and a compensation effect b
y thermally generated donors of the PA spectrum are investigated exten
sively. By considering these results, it is concluded that the observe
d peak is due to electron transitions involving boron acceptor impurit
ies. Low temperature spectra down to 90 K also support this conclusion
.