G. Oskam et al., THE INFLUENCE OF ELECTRODEPOSITED GOLD ON THE PROPERTIES OF III-V SEMICONDUCTOR ELECTRODES .3. RESULTS ON N-GAAS PROVIDED WITH THICK GOLD LAYERS, Electrochimica acta, 38(8), 1993, pp. 1115-1121
The influence of electrodeposited gold on the current-potential and im
pedance characteristics of n-GaAs electrodes was studied in various el
ectrolyte solutions. The potential of the gold layer on n-GaAs was mea
sured as a function of the bias applied to the electrode. It is conclu
ded that the same processes occur as previously proposed for gold-plat
ed p-GaAs electrodes. A model involving gold-related surface states wh
ich interact with both the valence band and the electrolyte solution w
as used to explain the results for p-GaAs. For n-GaAs, an additional p
rocess is found to play an important role recombination of thermally p
roduced holes with conduction band electrons.