KINETICS OF THE COMPLETE OXIDATION OF METHANE OVER THE CUZSM-5 CATALYST

Authors
NEKRASOV NV SLINKIN AA KUCHEROV AV BRAGINA GO KATSMAN EA KIPERMAN SL
Citation
Nv. Nekrasov et al., KINETICS OF THE COMPLETE OXIDATION OF METHANE OVER THE CUZSM-5 CATALYST, Kinetics and catalysis, 38(1), 1997, pp. 77-80
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
1
Year of publication
1997
Pages
77 - 80
Database
ISI
SICI code
0023-1584(1997)38:1<77:KOTCOO>2.0.ZU;2-V
Abstract
The kinetics of the methane complete oxidation over the CuZSM-5 cataly st was studied in a nongradient catalytic reactor. The reaction was sh own to proceed without diffusion control. The reaction rate is a funct ion of the CH4 concentration and does not depend on the concentrations of O-2 and CO2. However, the addition of water vapor results in a mar ked decrease in the reaction rate. The experimental data agree well wi th the reaction mechanism proposed.