CATALYTIC PROPERTIES AND PHASE-COMPOSITION OF PRODUCTS OF THERMAL-DECOMPOSITION OF PHOSPHOMOLYBDIC HETEROPOLYACID .3. EFFECT OF THE MEDIUM ON THERMOLYSIS OF HPA

Authors
BONDAREVA VM ANDRUSHKEVICH TV MAKSIMOVSKAYA RI PLYASOVA LM LITVAK GS BURGINA EB
Citation
Vm. Bondareva et al., CATALYTIC PROPERTIES AND PHASE-COMPOSITION OF PRODUCTS OF THERMAL-DECOMPOSITION OF PHOSPHOMOLYBDIC HETEROPOLYACID .3. EFFECT OF THE MEDIUM ON THERMOLYSIS OF HPA, Kinetics and catalysis, 38(1), 1997, pp. 106-111
Citations number
27
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
1
Year of publication
1997
Pages
106 - 111
Database
ISI
SICI code
0023-1584(1997)38:1<106:CPAPOP>2.0.ZU;2-Y
Abstract
It is shown by in situ X-ray diffraction analysis, IR spectroscopy, an d P-31 MAS NMR that the phase formation upon the thermal decomposition of phosphomolybdic heteropolyacid (H3PMo12O40 . 13H(2)O) depends on t he redox properties of the medium and the content of water vapor.