THE CRYSTAL-STRUCTURE OF 2-BENZOYLPYRIDINE N4-METHYL-N4-PHENYLTHIOSEMICARBAZONE

Authors
VALDESMARTINEZ J HERNANDEZORTEGA S WEST DX STARK AM BAIN GA
Citation
J. Valdesmartinez et al., THE CRYSTAL-STRUCTURE OF 2-BENZOYLPYRIDINE N4-METHYL-N4-PHENYLTHIOSEMICARBAZONE, Journal of chemical crystallography, 26(12), 1996, pp. 861-864
Citations number
12
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
26
Issue
12
Year of publication
1996
Pages
861 - 864
Database
ISI
SICI code
1074-1542(1996)26:12<861:TCO2N>2.0.ZU;2-3
Abstract
2-Benzoylpyridine N4-methyl-N4-phenylthiosemicarbazone, HBz4MePh, mono clinic, P2(1)/n, a = 9.141(2), b = 18.507(4), c = 11.401(2) Angstrom, beta = 110.58(3)degrees, V = 1805.6(9) Angstrom(3), Z = 4, mu = 1.655 mm(-1). HBz4MePh crystallizes in a hydrogen bonded Z isomeric conforma tion with respect to the C7-N2 bond. The intramolecular hydrogen bond is between N3-H ... N1, and the S atom is Z to the azomethine nitrogen , N2.