Scanning tunneling microscopy (STM) has been used to image at atomic r
esolution the surface of pyrocarbons deposited at 1680-degrees-C and h
eat-treated at temperatures up to 2800-degrees-C. Information is obtai
ned on the increase of surface order with HTT. Of special interest are
the presence, in HTT 2000 samples, of point defects arranged in a (sq
uare-root 7 x square-root 7) R 19. 1-degrees superstructure and attrib
uted to an array of interstitial carbon atoms, and the observation of
a moire pattern in the HTT 2200 sample, which could be due to the turb
ostratic nature of the layer stacking.