Radial distribution analysis of X-ray intensities diffracted by natura
l coir fibre subjected to various thermal and mercerization treatments
has been carried out. Interatomic distances, mean square displacement
s and interatomic coupling constants have been obtained from the radia
l distribution curves. As coir fibre finds its various applications in
its natural form, its study has been carried out without disturbing t
he configuration of its cellulose-lignin complex during the treatments
. Interatomic distances remain more or less the same during thermal an
d chemical treatments but the coupling constants and the mean square d
isplacements experience changes, reflecting the changed mechanical beh
aviour of the fibre.