We have investigated the possibility of pyrrole oligomerization within
zeolite channels in acid zeolites containing Fe3+ to study the action
of acid and one-electron oxidation polymerization mechanisms together
. We also indicate the possibility of preparing materials with electri
cal conductivities varying within a wide range based on the combined a
dsorption of pyrrole and water in acid zeolites. Further it is shown t
hat pyrrole polymerization is possible at the surface of amorphous alu
minosilicates with the consequent generation of a hydrophobic surface.