L. Morawska et Cr. Phillips, DEPENDENCE OF THE RADON EMANATION COEFFICIENT ON RADIUM DISTRIBUTION AND INTERNAL STRUCTURE OF THE MATERIAL, Geochimica et cosmochimica acta, 57(8), 1993, pp. 1783-1797
The mechanisms of escape of radon from the solid structure of a partic
le to the free pore space are examined. According to the present state
of knowledge, the most important factors affecting the radon emanatio
n coefficient are the distribution of the parent radium atoms and the
internal structure of the material. In early studies of the radon eman
ation coefficient, it was usually assumed that the material under inve
stigation was homogeneous in radium distribution and in internal struc
ture. It is now known that these assumptions are often not justified f
or real materials. In consequence, models based on these assumptions m
ay not be useful in explaining the emanation process. The importance o
f radium distribution and internal structure is explained here, and an
analysis made of differences in the internal structure of various nat
ural and man-made materials. The analysis is then developed in order t
o identify the effect of different models of radium atom distribution
on the emanation coefficient. Four models of radium atom distribution
are presented, together with mathematical approaches for developing an
d finding numerical solutions for equations leading to determination o
f the emanation coefficient for each model.