CARRIER CONCENTRATIONS AND RELAXATION SPECTROSCOPY - NEW INFORMATION FROM SCALING PROPERTIES OF CONDUCTIVITY SPECTRA IN IONICALLY CONDUCTING GLASSES

Citation
B. Roling et al., CARRIER CONCENTRATIONS AND RELAXATION SPECTROSCOPY - NEW INFORMATION FROM SCALING PROPERTIES OF CONDUCTIVITY SPECTRA IN IONICALLY CONDUCTING GLASSES, Physical review letters, 78(11), 1997, pp. 2160-2163
Citations number
40
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
78
Issue
11
Year of publication
1997
Pages
2160 - 2163
Database
ISI
SICI code
0031-9007(1997)78:11<2160:CCARS->2.0.ZU;2-2
Abstract
A new kind of scaling analysis for the conductivity spectra of glasses without any arbitrary parameters is presented. By applying this metho d to sodium berate glasses of different compositions, we find strong i ndications for the existence of a universal ionic relaxation process a s well as for a strong electrolyte behavior. Our results enable us to show that the often used electric modulus formalism is misleading when relaxation mechanisms on a microscopic level are concerned. A more me aningful discussion can be based on the log-log dependence of the cond uctivity on frequency.