B. Roling et al., CARRIER CONCENTRATIONS AND RELAXATION SPECTROSCOPY - NEW INFORMATION FROM SCALING PROPERTIES OF CONDUCTIVITY SPECTRA IN IONICALLY CONDUCTING GLASSES, Physical review letters, 78(11), 1997, pp. 2160-2163
A new kind of scaling analysis for the conductivity spectra of glasses
without any arbitrary parameters is presented. By applying this metho
d to sodium berate glasses of different compositions, we find strong i
ndications for the existence of a universal ionic relaxation process a
s well as for a strong electrolyte behavior. Our results enable us to
show that the often used electric modulus formalism is misleading when
relaxation mechanisms on a microscopic level are concerned. A more me
aningful discussion can be based on the log-log dependence of the cond
uctivity on frequency.