DIFFUSION-LIMITED PROCESSES ON FRACTAL SURFACES GENERATED AS A SET OFSCALED WALSH-FUNCTIONS

Citation
S. Zalis et al., DIFFUSION-LIMITED PROCESSES ON FRACTAL SURFACES GENERATED AS A SET OFSCALED WALSH-FUNCTIONS, Journal of electroanalytical chemistry [1992], 349(1-2), 1993, pp. 443-452
Citations number
22
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
349
Issue
1-2
Year of publication
1993
Pages
443 - 452
Database
ISI
SICI code
Abstract
The Mote Carlo technique was used for modelling mass transport to frac tal electrode surfaces under conditions of a potentiostatic pulse and linear scan voltammetry. Fractal surfaces of different fractal dimensi on D were constructed using the Walsh-Hadamard transform. The effects of surface geometry on the form of the current response and long-time cut-off are discussed with respect to the validity of diagnostic proce dures used for the electrode kinetics on smooth electrodes.