EVIDENCE OF AN ELASTIC INSTABILITY BETWEEN THE AMORPHOUS AND THE MICROCRYSTALLINE STATE OF CA-MODIFIED LEAD TITANATE AS REVEALED BY BRILLOUIN SPECTROSCOPY
Jk. Kruger et al., EVIDENCE OF AN ELASTIC INSTABILITY BETWEEN THE AMORPHOUS AND THE MICROCRYSTALLINE STATE OF CA-MODIFIED LEAD TITANATE AS REVEALED BY BRILLOUIN SPECTROSCOPY, Physical review letters, 78(11), 1997, pp. 2240-2243
Brillouin spectroscopy was used to probe the hypersonic properties of
Ca-modified lend titanate between the purl amorphous and the coarse gr
ained state. The samples were thin films rf sputtered onto (100)-silic
on wafer at ambient temperature, followed by an annealing process in t
he range from 673 to 873 K. An elastic instability of the longitudinal
ly polarized sound mode suggests the existence of a discontinuous stru
ctural transformation from the amorphous to the nanostructure state.