MASS-SPECTROMETRIC STUDY OF SOME 2,3-DIARYL-1,3-THIAZOLIDIN-4-ONES UNDER ELECTRON-IMPACT

Citation
Crj. Woolston et al., MASS-SPECTROMETRIC STUDY OF SOME 2,3-DIARYL-1,3-THIAZOLIDIN-4-ONES UNDER ELECTRON-IMPACT, Organic mass spectrometry, 28(4), 1993, pp. 445-450
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear",Spectroscopy
Journal title
ISSN journal
0030493X
Volume
28
Issue
4
Year of publication
1993
Pages
445 - 450
Database
ISI
SICI code
0030-493X(1993)28:4<445:MSOS2U>2.0.ZU;2-F
Abstract
The mass spectral fragmentations of some 2,3-diaryl-1,3-thiazolidin-4- ones were established by comparing spectra and by using exact mass mea surements. The major fragment ions were identified and their relative importances related to substituent effects and bond strengths. Good co rrelations were observed between the relative abundances of some of th e breakdown products and the Hammett sigma constants of substituents i n the aromatic rings.