Tn. Sidorina et al., HIGH-TEMPERATURE DUCTILITY OF N65M TYPE CORROSION-RESISTANT ALLOY MELTED IN VARIOUS WAYS, Metal science and heat treatment, 34(11-12), 1992, pp. 752-757
The influence of various deoxidation and microalloying options on the
high-temperature ductility and structure of the N65M type corrosion re
sistant alloy melted in various ways has been examined It is demonstra
ted that the ductility level is determined first and foremost by the g
rain boundaries condition, and in many respects by the presence of har
mful impurities segregation at the grain boundaries, and particularly,
carbon. The latter promotes M12C type carbides precipitation in volum
es at the grain boundary regions. Surfactant elements (Mg, B) added in
optimum amounts attenuate grain boundary segregation by carbon, modif
y the breakdown kinetics at the grain boundaries and hamper the format
ion of carbide precipitates there. A combination of these effects resu
lts in a change in the failure mechanism and an increase in the high-t
emperature ductility by a two to threefold factor. Recommendations con
cerning alloy melting procedures are made.