Microporous carbon membranes are prepared, characterised structurally
and tested in terms of high pressure CO2 permeability at temperatures
around the critical. A maximum in the permeance versus relative pressu
re curve is observed in close analogy to the case of mesoporous membra
nes. This weakens considerably as the temperature is increased above t
he critical. The results offer significant input for an improved under
standing and theoretical modelling of the process and may be potential
ly useful for the identification of the optimal pressure and temperatu
re conditions for efficient gas separations.