Lhm. Dasilva et al., EQUILIBRIUM PHASE-BEHAVIOR OF POLY(ETHYLENE GLYCOL) PLUS POTASSIUM PHOSPHATE PLUS WATER 2-PHASE SYSTEMS AT VARIOUS PH AND TEMPERATURES, Journal of chemical and engineering data, 42(2), 1997, pp. 398-401
This work presents the effects of changes in temperature (4 degrees C,
25 degrees C, and 40 degrees C), pH (6, 7, and 9), and polymer molecu
lar weight (1000 and 8000) on the equilibrium phase behavior of two-ph
ase PEG + potassium phosphate + water systems. As the temperature and
pH were increased, the binodal curve shifted to lower polyethylene and
phosphate concentrations, resulting in a higher difference in polymer
and salt concentrations between the top and bottom phases. This corre
sponds to an increase in the region of two-phase coexistence.