FACILE [3,3]-SIGMATROPIC REARRANGEMENT IN THE REACTION OF ALPHA-CHLOROPERFLUOROSTYRENE WITH ALLYL ALCOHOL

Authors
ANDREEV VG KOLOMIETS AF DVORNIKOVA KV PLATONOV VE
Citation
Vg. Andreev et al., FACILE [3,3]-SIGMATROPIC REARRANGEMENT IN THE REACTION OF ALPHA-CHLOROPERFLUOROSTYRENE WITH ALLYL ALCOHOL, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(8), 1992, pp. 1509-1510
Citations number
3
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
8
Year of publication
1992
Part
2
Pages
1509 - 1510
Database
ISI
SICI code
1063-5211(1992)41:8<1509:F[RITR>2.0.ZU;2-P
Abstract
The reaction of alpha-chloroperfluorostyrene (1) with allyl alcohol in the presence of KOH at 45-50-degrees-C leads to a mixture of the ally l 2-pentafluorophenyl-2-chloro-4-pentenoate (2) and the product of the addition of the starting reagents (3). Ester 2 is formed as the resul t of a mild [3,3]-sigmatropic rearrangement of the reaction intermedia te.