ACTIVE HYDROGEN ON THE SURFACE OF ULTRADISPERSED CARBON

Citation
Tm. Gubarevich et al., ACTIVE HYDROGEN ON THE SURFACE OF ULTRADISPERSED CARBON, Journal of applied chemistry of the USSR, 65(6), 1992, pp. 1051-1054
Citations number
10
Categorie Soggetti
Chemistry Applied
ISSN journal
0021888X
Volume
65
Issue
6
Year of publication
1992
Part
1
Pages
1051 - 1054
Database
ISI
SICI code
0021-888X(1992)65:6<1051:AHOTSO>2.0.ZU;2-R
Abstract
The interaction between methylmagnesium iodide in anisole and surface functional groups of ultradispersed diamond-containing powders (UDD) c an be divided into three stages: interaction with molecular additives and the-external surface; interaction with the surface of open pores; and interaction with the surface exposed during mechanicochemical brea kdown of the UDD aggregates. The quantitative characteristics of the U DD surface have been determined: density of protonated groups (0.34-2. 52 mug-eq/m2) and concentration of active hydrogen (0.49-7.52 mug-eq/m 2).