ORGANOMETAL CHEMISTRY OF TECHNETIUM .8. TECHNETIUM(I) CARBONYL-COMPLEXES WITH POLYPYRAZOL-1-YLBORATO LIGANDS IN COMPARISON WITH MN AND RE ANALOGS

Authors
JOACHIM JE APOSTOLIDIS C KANELLAKOPULOS B MAIER R MARQUES N MEYER D MULLER J DEMATOS AP NUBER B REBIZANT J ZIEGLER ML
Citation
Je. Joachim et al., ORGANOMETAL CHEMISTRY OF TECHNETIUM .8. TECHNETIUM(I) CARBONYL-COMPLEXES WITH POLYPYRAZOL-1-YLBORATO LIGANDS IN COMPARISON WITH MN AND RE ANALOGS, Journal of organometallic chemistry, 448(1-2), 1993, pp. 119-129
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
448
Issue
1-2
Year of publication
1993
Pages
119 - 129
Database
ISI
SICI code
0022-328X(1993)448:1-2<119:OCOT.T>2.0.ZU;2-E
Abstract
The compounds HB(C3H3N2)3Tc(CO)3 and HB(3,5-Me2C3HN2)3Tc(CO)3 have bee n synthesized for the first time, and their molecular and crystal stru cture as well as the structures of the known analogous compounds of ma nganese and rhenium determined by single-crystal X-ray diffraction. Th e IR-, H-1-NMR-, C-13-NMR-, UV- and EI-MS-spectroscopic data are discu ssed in correlation to the electric dipole moment and the charge distr ibution within the molecule.