SYNTHESIS, AND SPECTRAL AND X-RAY STRUCTURAL STUDIES OF A NOVEL DELOCALIZED TRIPHOSPHAZENE (CF3)2P=N=P(CF3)2=N=PPH3 AND THE TRIOSMIUM CLUSTER COMPLEX OS3(CO)11[(CF3)2P=N=P(CF3)2=N=PPH3]

Authors
ANG HG CAI YM KWIK WL
Citation
Hg. Ang et al., SYNTHESIS, AND SPECTRAL AND X-RAY STRUCTURAL STUDIES OF A NOVEL DELOCALIZED TRIPHOSPHAZENE (CF3)2P=N=P(CF3)2=N=PPH3 AND THE TRIOSMIUM CLUSTER COMPLEX OS3(CO)11[(CF3)2P=N=P(CF3)2=N=PPH3], Journal of organometallic chemistry, 448(1-2), 1993, pp. 219-223
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
448
Issue
1-2
Year of publication
1993
Pages
219 - 223
Database
ISI
SICI code
0022-328X(1993)448:1-2<219:SASAXS>2.0.ZU;2-0
Abstract
The triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 (L), prepared by the react ion of (CF3)PN3 with (CF3)2P=N=PPh3, has bee found to afford the clust er [Os3(CO)11{(CF3)2P=N=P(CF3)2=N=PPh3}] (1) with [Os3(CO)11(MeCN)]. B oth L and 1 have been show by X-ray crystallography to have an unusual and highly delocalised P=N=P=N=P moiety containing P(IV), P(V) and P( VI) atoms.