J. Sonnefeld et al., THE INFLUENCE OF THE CHOICE OF A SUITABLE DIVIDING SURFACE ON THE RESULTS OF SURFACE-CHARGE DENSITY CALCULATIONS, Zeitschrift für physikalische Chemie, 176, 1992, pp. 199-209
Citations number
19
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
The model of site dissociation of acid surface groups is used in conne
ction with the Gouy-Chapman model of the electrical double-layer for t
he calculation of theoretical values of the surface charge density of
spherical particles in aqueous electrolyte solutions. The influence of
a parameter delta on the particle size dependence of the surface char
ge density is discussed. Delta is the distance between the plane of th
e location of the surface charge and the equimolecular dividing surfac
e of the monolayer adsorption of gases.