The electrical properties of Co1-xZnxFe2O4 (x=0-1) spinel ferrites wer
e investigated by impedance spectroscopy. The grain-boundary resistanc
e was found to increase as a function of composition up to x=0.6, and
decreases beyond x=0.6. The variation in the bulk resistance and the a
ctivation energy as a function of composition is found to exhibit a si
milar trend whereas the grain resistance appears to be an independent
parameter. The observed results suggest that the bulk properties of so
lid solution spinel ferrites are primarily controlled by the grain-bou
ndary phase.