Ma. Baute et al., ENZYMATIC-ACTIVITY DEGRADING 1,4-ALPHA-D-GLUCANS TO ASCOPYRONES P ANDT IN PEZIZALES AND TUBERALES, Phytochemistry, 33(1), 1993, pp. 41-45
When subjected to 'activating' plasmolytic treatments, several Ascomyc
etes exhibit an enzymic activity which degrades 1,4-alpha-D-glucans to
1,5-D-anhydrofructose, then converts this sugar to ascopyrone P (in P
ezizales) or ascopyrone T (in Tuberales). Biogenetical, mycological an
d practical implications of these bioconversions are discussed.