The exchange splitting of image-induced surface states on Fe(110) is c
alculated by spin-polarized near-surface embedding. The splitting is 5
5 meV for the n = 1 state and is primarily a result of coupling to the
spin-polarized substrate potential. The effect of the spin-polarized
surface barrier is relatively small and of opposite sign to the substr
ate contribution. This surprising result is a direct consequence of th
e negative spin density of surface electrons at the Fermi energy, illu
strating the sensitivity of spin-split image states to surface magneti
c properties.