BOROSILICATE COMPOUNDS OF THE TYPE H2N(CH2)3OB(R)(OSIR3') - THE STRUCTURE OF DIMETHYLPHENYLSILOXY)-2-PHENYL-1,3,2-OXAZABORINANE

Authors
FERGUSON G GALLAGHER JF MURPHY D SHEEHAN JP SPALDING TR
Citation
G. Ferguson et al., BOROSILICATE COMPOUNDS OF THE TYPE H2N(CH2)3OB(R)(OSIR3') - THE STRUCTURE OF DIMETHYLPHENYLSILOXY)-2-PHENYL-1,3,2-OXAZABORINANE, Polyhedron, 12(8), 1993, pp. 859-864
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
8
Year of publication
1993
Pages
859 - 864
Database
ISI
SICI code
0277-5387(1993)12:8<859:BCOTTH>2.0.ZU;2-N
Abstract
The syntheses of compounds of the types H2N(CH2)3OB(Ph)(OSiR3')[R3' = Me3 (1), Me2Ph (2), McPh2 (3), Ph3 (4)] and H2N(CH2)3OB(Bu)(OSiR3') [R 3' = Me2Ph (5), MePh2 (6), Ph3 (7)] arc reported. The structure of 2 w as determined by X-ray crystallography. There are two independent mole cules in the unit cell. Both molecules contain tetrahedral BCNO2- and SiC3O- units joined by B-O-Si bridges with angles of 145.7(3)-degrees and 150.5(3)-degrees, respectively. In solution compounds 1-7 are invo lved in intramolecular equilibrium reactions between four- and three-c oordinate boron species with the latter formed by scission of the B-N bond.