Amphoteric polymers which have cationic properties at acidic pH, but a
re neutral or anionic at alkaline pH, have been prepared and tested fo
r water clarification and decolourization. The polymer is an adjunct t
o a magnetic iron oxide employed as the primary coagulant, which is re
cycled after alkaline treatment. A range of structures has been invest
igated, including copolymers of methacrylic acid with various quaterna
ry ammonium monomers, terpolymers of these with methyl methacrylate as
the third monomer, and polymers containing phenolic or amino acid moi
eties as well as quaternary ammonium sites. The last two groups of pol
ymers were the most effective in enhancing water treatment performance
, with concomitant facile regeneration behaviour.