TRANSITION-METAL COMPLEXES FEATURING A DIAZO GROUP ON A LIGAND - X-RAY CRYSTAL-STRUCTURE OF [EXO-(ME3SICN2)-ETA(5)-C6H6]MN(CO)3

Authors
REAU R REED RW DAHAN F BERTRAND G
Citation
R. Reau et al., TRANSITION-METAL COMPLEXES FEATURING A DIAZO GROUP ON A LIGAND - X-RAY CRYSTAL-STRUCTURE OF [EXO-(ME3SICN2)-ETA(5)-C6H6]MN(CO)3, Organometallics, 12(5), 1993, pp. 1501-1502
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
5
Year of publication
1993
Pages
1501 - 1502
Database
ISI
SICI code
0276-7333(1993)12:5<1501:TCFADG>2.0.ZU;2-L
Abstract
[Bis(diisopropylamino)thioxophosphoranyl]-and (trimethylsilyl)diazomet hane lithium salts react with [(C6H6)Mn(CO)3]+PF6-, leading to [exo-(R CN2)-eta5-C6H5]Mn(CO)3 (4, R = (i-Pr2N)2P(S); 5, R = Me3Si), the first complexes with a diazo-functionalized ligand.