NOVEL C-C BOND FORMATION REACTIONS MEDIATED BY (OXAALLYL)MOLYBDENUM COMPLEXES

Authors
FALLER JW MA YN
Citation
Jw. Faller et Yn. Ma, NOVEL C-C BOND FORMATION REACTIONS MEDIATED BY (OXAALLYL)MOLYBDENUM COMPLEXES, Organometallics, 12(5), 1993, pp. 1927-1930
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
5
Year of publication
1993
Pages
1927 - 1930
Database
ISI
SICI code
0276-7333(1993)12:5<1927:NCBFRM>2.0.ZU;2-5
Abstract
Treatment Of MO(CO)3(NCMe)3 with a-chloroacetophenone yields intermedi ate aldol condensation products that can be trapped as stable cyclopen tadienyl complexes. The reactions are highly stereoselective and give predominantly one isomer of each product. CpMo(CO)2[eta3-CH2C(Ph)=CH(C OPh)] and CPMO(CO)2[eta3-CH2C(Ph)CHC(Ph)=CH(COPh)] were isolated and c haracterized by X-ray crystallography.