EFFICIENT NEW SYNTHETIC ROUTE TO BIDENTATE, MONOMERIC CYCLOPENTADIENYL AMIDE COMPLEXES OF GROUP-4 TRANSITION-METALS - SYNTHESIS AND CHARACTERIZATION OF THE ZIRCONIUM AND HAFNIUM COMPLEXES [(ETA(5)-SIGMA-C5H4(CH2)3NME)MX2(NHME2)] (X = CL, I, M = ZR - X = I, M = HF) AND [(ETA(5)-SIGMA-C5H4(CH2)3NME)ZRX2] (X = NME2, CH2PH, CH2SIME3, BH4) AND MOLECULAR-STRUCTURE OF [(ETA(5)-SIGMA-C5H4(CH2)3NME)ZRCL(CH2PH)]2

The synthesis of the amine-substituted cyclopentadiene C5H5CH2CH2CH2N( H)Me (2, HCpNH) is described. The reaction of 2 with M(NMe2)4 (M = Zr, Hf) gives the ring-closed species [M(eta5:sigma-C5H4CH2CH2CH2NMe)(NMe 2)2] (M(CpN)(NMe2)2; M = Zr (3), Hf (4)) in high yields (60-95 %). Ami nolysis of 3 and 4 with 2 equiv of Me2NH.HX (X = Cl, I) provides a rou te to amine adducts of the dihalide complexes [M(CpN)X2(NHMe2)] (M = Z r, X = Cl (5), I (6); M = Hf, X = I (7)). Aminolysis of 3 with 1 equiv of Me2NH.HI gives the mixed amido-iodide [Zr(CpN)I(NMe2)] (8). The di chloride 5 is an excellent precursor to alkyl complexes; thus, reactio n of 5 with C6H5CH2MgCl (2 equiv) gives [Zr(CpN)(CH2Ph)2] (9), that of 5 with Me3-SiCH2Li gives [Zr(CpN)(CH2SiMe3)2] (10), and that of 5 wit h C6H5CH2MgCl (1 equiv) gives the mixed complex [Zr(CpN)(CH2Ph)Cl] (11 ). The H-1 and C-13 NMR data for 9 and 10 are discussed in terms of et a2-benzyl (9) and agostic (10) interactions in these formally 14-valen ce-electron compounds. The reaction of 5 with LiBH4 gives [Zr(CpN)(eta 3-BH4)2] (13). Aminolysis of 3 with cyclopentadiene gives [Zr(CpN)(eta -C5H5)(NMe2)] (14), while 3 also reacts with phenylacetylene to give t he poorly stable bis(acetylide) [Zr(CpN)(CCPh)2] (15). Compound 11 has been characterized as a benzene-d6 solvate by X-ray crystallography: (C32H40Cl2N2Zr2)0.5-(C6D6), M(r) = 437.17, monoclinic, P2(1)/c, a = 11 .649(1) angstrom, b = 10.360(1) angstrom, c = 17.802(1) angstrom, 106. 750(4)-degrees, V = 2057.3(3) angstrom3, Z = 4, D(x) = 1.411 g cm-3, l ambda(Mo KalphaBAR) = 0.710 73 angstrom, mu = 6.6 cm-1, F(000) = 888, T = 295 K, and R(F) = 0.035 for 3691 unique observed reflections with I greater-than-or-equal-to 2.5sigma(I) and 260 parameters. The crystal structure consists of dimer molecules of 11, obeying symmetry 1BAR an d coupled by two bridging Cl atoms, with two different Zr-Cl distances of 2.6288(8) and 2.6797(9) angstrom, respectively.