THE 1ST CATALYTIC ENANTIOSELECTIVE SYNTHESIS OF (R)-(+) LASIODIPLODIN

Authors
JONES GB HUBER RS
Citation
Gb. Jones et Rs. Huber, THE 1ST CATALYTIC ENANTIOSELECTIVE SYNTHESIS OF (R)-(+) LASIODIPLODIN, Synlett, (5), 1993, pp. 367-368
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1993
Pages
367 - 368
Database
ISI
SICI code
0936-5214(1993):5<367:T1CESO>2.0.ZU;2-O
Abstract
The first catalytic enantioselective route to (R)-(+) Lasiodiplodin is described. Introduction of the asymmetric center was accomplished by the enantioselective addition of dimethyl zinc to an aldehyde, mediate d by a tricarbonyl (eta6 arene) chromium(0) catalyst.