DYNAMICS OF RODLIKE POLYMERS IN DILUTE-SOLUTION

Citation
Jb. Avalos et al., DYNAMICS OF RODLIKE POLYMERS IN DILUTE-SOLUTION, Macromolecules, 26(10), 1993, pp. 2550-2561
Citations number
34
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00249297
Volume
26
Issue
10
Year of publication
1993
Pages
2550 - 2561
Database
ISI
SICI code
0024-9297(1993)26:10<2550:DORPID>2.0.ZU;2-R
Abstract
In this paper we calculate the translational and rotational friction c oefficients for a suspended rigid rod as well as its contribution to t he viscosity in the dilute limit as a function of the aspect ratio. In the long rod limit the asymptotic behavior is found to be identical t o Yamakawa's expressions. For finite rods, our results, in particular those for the translational friction coefficient, reproduce numerical values obtained by Tirado et al. and differ from the values obtained b y Broersma using the Oseen-Burgers approximation and from the values o btained later using the slender body theory.