Molecular beam epitaxy of CaF2 monocrystalline layers Er3+ doped up to
a concentration of 5 wt % is demonstrated on CaF2 substrates. Separat
ed effusion cells containing CaF2 and ErF3 were used. The photolumines
cence spectra of the samples show emissions from centers of different
symmetry identified by reference to published results obtained on CaF2
:Er3+ bulk crystals. No influence of the substrate orientation-(100) o
r (111)-on the luminescence characteristics was observed.