K. Imai et al., SEPARABILITY OF SO2 FROM SO2 N2 MIXTURE THROUGH SULFOXIDE-MODIFIED POLY(VINYL ALCOHOL) AND CELLULOSE MEMBRANES/, Journal of applied polymer science, 48(9), 1993, pp. 1525-1529
Separability of SO2 from mixtures of SO2 and N2 gases was studied for
membranes of poly (vinyl alcohol) (PVA) and cellulose modified with me
thyl, ethyl, t-butyl, and phenyl vinyl sulfoxides. Of these sulfoxide-
modified polymers, the phenyl vinyl sulfoxide-modified PVA membranes w
ere found to give the best separation of SO2. In the phenyl vinyl sulf
oxide-modified PVA membranes, the permeability coefficient of SO2 incr
eased with sulfoxide content while separability of SO2 was maximum at
a sulfoxide content of 23.5 mol %; the separation factor of SO2 was ab
out 170 at this sulfoxide content.