MECHANICAL AND THERMAL-BEHAVIOR OF COTTON CELLULOSE GRAFT-COPOLYMERIZED USING HYDROXYETHYL METHACRYLATE IN PRESENCE OF TRIETHYLENE GLYCOL DIMETHACRYLATE
Sr. Shukla et Ar. Athalye, MECHANICAL AND THERMAL-BEHAVIOR OF COTTON CELLULOSE GRAFT-COPOLYMERIZED USING HYDROXYETHYL METHACRYLATE IN PRESENCE OF TRIETHYLENE GLYCOL DIMETHACRYLATE, Journal of applied polymer science, 48(11), 1993, pp. 1877-1883
UV-radiation-induced graft-copolymerization of cotton cellulose was ca
rried out with 2-hydroxyethyl methacrylate (HEMA) in the presence of s
mall amounts of triethylene glycol dimethacrylate (TEGDMA) using benzo
in ethyl ether (BEE), uranyl nitrate (UN), and ceric ammonium nitrate
(CAN) as photoinitiators. The presence of very small amounts of TEGDMA
in the HEMA grafting bath led to great enhancement in the graft add-o
n as compared to that obtained on the sodium hydroxide-preswollen subs
trate. With increase in the graft add-on, the breaking load of cotton
decreased, whereas its thermal stability improved.