NON-POLYMERIC MOLYBDENUM(II) COMPLEXES OF DICARBOXYLIC-ACIDS - SYNTHESIS, STRUCTURE AND CATALYTIC PROPERTIES

Authors
WHELAN E DEVEREUX M MCCANN M MCKEE V
Citation
E. Whelan et al., NON-POLYMERIC MOLYBDENUM(II) COMPLEXES OF DICARBOXYLIC-ACIDS - SYNTHESIS, STRUCTURE AND CATALYTIC PROPERTIES, Chemical communications, (5), 1997, pp. 427-428
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1997
Pages
427 - 428
Database
ISI
SICI code
1359-7345(1997):5<427:NMCOD->2.0.ZU;2-F
Abstract
[Mo-2(MeCN)(8)][BF4](4) reacts with alpha,omega-dicarboxylic acids [HO 2C(CH2)(n)CO2H, n = 0-8] to form salts with empirical formula [Mo-2{O2 C(CH2)(n)CO2}(MeCN)(x)][BF4](2); the X-ray crystal structure of the bu tanedioic salt u-O2C-(CH2)(2)CO2-mu-eta(2)}(2)(MeCN)(12)][BF4](4) . 3M eCN is reported together with the use of the complexes as catalysts fo r the polymerization of norbornene.