DYNAMICS OF H D AND D/H EXCHANGES IN BETA-CYCLODEXTRIN DODECAHYDRATE OBSERVED IN REAL-TIME - EFFECTS FROM ZERO-POINT VIBRATIONAL-ENERGY/

Authors
DASILVA AM STEINER T SAENGER W EMPIS J TEIXEIRADIAS JJC
Citation
Am. Dasilva et al., DYNAMICS OF H D AND D/H EXCHANGES IN BETA-CYCLODEXTRIN DODECAHYDRATE OBSERVED IN REAL-TIME - EFFECTS FROM ZERO-POINT VIBRATIONAL-ENERGY/, Chemical communications, (5), 1997, pp. 465-466
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1997
Pages
465 - 466
Database
ISI
SICI code
1359-7345(1997):5<465:DOHDAD>2.0.ZU;2-Z
Abstract
Cyclic H/D and D/H exchange processes in crystalline beta-cyclodextrin dodecahydrate exposed to D2O (or H2O) vapour, monitored in real time by the integrated intensity of the O-H Raman stretching band, exhibit different rate constants and activation energies ascribed to different zero-point vibrational energies of OH and OD.