COPPER DIOXYGEN COMPLEXES STABLE AT AMBIENT-TEMPERATURE - OPTIMIZATION OF LIGAND DESIGN AND SOLVENT

Authors
KARLIN KD LEE DH KADERLI S ZUBERBUHLER AD
Citation
Kd. Karlin et al., COPPER DIOXYGEN COMPLEXES STABLE AT AMBIENT-TEMPERATURE - OPTIMIZATION OF LIGAND DESIGN AND SOLVENT, Chemical communications, (5), 1997, pp. 475-476
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1997
Pages
475 - 476
Database
ISI
SICI code
1359-7345(1997):5<475:CDCSAA>2.0.ZU;2-Z
Abstract
Entropic destabilization of low-molecular mass mu-peroxodicopper(II) c omplexes are overcome using a new binucleating open-chain ligand by th e combination of an optimized linking unit with a less competing solve nt; complete formation and satisfactory stability at room temperature are thus obtained.