The field of low-energy ion scattering for surface interactions at met
als, alloys, catalysts and semiconductors is reviewed. The description
of experimental set-up's for ion and neutral detection has been inclu
ded. One of the topics is ion scattering for elemental analysis of the
topmost layer to be performed in the classical noble-gas ion scatteri
ng spectroscopy approach (ISS) as well as with direct recoil spectrosc
opy (DRS). Emphasis has also been put on surface structure analysis in
cluding ion beam crystallography with low-energy ion backscattering (I
CISS) for single-crystal surfaces. The basic principles, classical sca
ttering theory, the effect of shadowing and blocking, and some of the
computer simulation programs are briefly described. A discussion for u
nderstanding the physics of ion-surface interactions, charge exchange
of various projectiles during collisions, molecule scattering and bond
breaking is also included.