MOLECULAR COMBINATIONS OF TETRACYANOETHYLENE WITH AMINOACETANILIDE

Citation
Em. Vasilescu et M. Iovu, MOLECULAR COMBINATIONS OF TETRACYANOETHYLENE WITH AMINOACETANILIDE, Revue Roumaine de Chimie, 38(1), 1993, pp. 59-64
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00353930
Volume
38
Issue
1
Year of publication
1993
Pages
59 - 64
Database
ISI
SICI code
0035-3930(1993)38:1<59:MCOTWA>2.0.ZU;2-M
Abstract
By choosing some donors of the aminoacetanylide class which include in their molecule various groups of atoms with n and pi orbitals evidenc e the participation of various molecular structures in the formation o f molecular combinations by charge transfer (CT) were evidenced these structures influencing each other. As acceptor we used tetracyanoethyl ene (TCNE). The domain of formation for complex of the type DA, D2A, D A2 according to the ratio D/A was established. For the 1 : 1 complex t he equilibrium constat was determined.