Nv. Pogodina, ORIENTATIONAL DEFORMATIONAL NATURE OF FLOW BIREFRINGENCE IN SOLUTIONSOF RIGID-CHAIN POLYMERS, Journal of polymer science. Part B, Polymer physics, 31(7), 1993, pp. 795-802
The orientational-deformational nature of flow birefringence (FB) in s
olutions of rigid-chain polymers is confirmed experimentally. The poss
ibility of a direct determination of the internal viscosity parameter
by the dependence of the FB relaxation time on the solvent viscosity i
s demonstrated. Indirect manifestation of internal viscosity in the FB
relaxation time is confirmed by the dependence of the form factor on
the degree of coiling.