A RAPID COBALT CARBONYL MEDIATED CLEAVAGE OF BOTH PHOSPHORUS CARBON BONDS IN BIS(DIPHENYLPHOSPHINO)METHANE UNDER VERY MILD CONDITIONS - EXTRUSION OF METHYLENE AS KETENE

Authors
AHMED S HOLAH DG HUGHES AN MARKEWICH RT
Citation
S. Ahmed et al., A RAPID COBALT CARBONYL MEDIATED CLEAVAGE OF BOTH PHOSPHORUS CARBON BONDS IN BIS(DIPHENYLPHOSPHINO)METHANE UNDER VERY MILD CONDITIONS - EXTRUSION OF METHYLENE AS KETENE, Polyhedron, 12(9), 1993, pp. 1101-1102
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
9
Year of publication
1993
Pages
1101 - 1102
Database
ISI
SICI code
0277-5387(1993)12:9<1101:ARCCMC>2.0.ZU;2-8
Abstract
In obalt(II)/{bis(diphenylphosphino)methane}/NaBH4/CO reactions, in wh ich the NaBH4 is added very rapidly, both P-C bonds of the phosphine a re cleaved with extrusion of the methylene group as ketene.