The application of a disjoint principal-components regression method t
o the analysis of sensor-array response patterns is demonstrated using
published data from ten polymer-coated surface-acoustic-wave (SAW) se
nsors exposed to each of nine vapors. Use of the method for the identi
fication and quantitation of the components of vapor mixtures is shown
by simulating the 36 possible binary mixtures and 84 possible ternary
mixtures under the assumption of additive responses. Retaining inform
ation on vapor concentrations in the classification models allows vapo
rs to be accurately identified, while facilitating prediction of the c
oncentrations of individual vapors and the vapors comprising the mixtu
res. The effects on the rates of correct classification of placing con
straints on the maximum and minimum vapor concentrations and superimpo
sing error on the sensor responses are investigated.