SPECIFIC FUNCTIONALIZATION ON THE SURFACE OF DENDRIMERS

Authors
SLANY M CAMINADE AM MAJORAL JP
Citation
M. Slany et al., SPECIFIC FUNCTIONALIZATION ON THE SURFACE OF DENDRIMERS, Tetrahedron letters, 37(50), 1996, pp. 9053-9056
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
50
Year of publication
1996
Pages
9053 - 9056
Database
ISI
SICI code
0040-4039(1996)37:50<9053:SFOTSO>2.0.ZU;2-V
Abstract
A specific monosubatitution on each P(X)(NH-CH2-CH=CH2)(2) terminal gr oup (X = O, S) of phosphorus dendrimers is described from generation 1 to generation 7. This reaction allows to isolate compounds which poss ess simultaneously up to 192 phosphine, 192 N-H and 384 allyl groups. Preliminary experiments show that these functionalized dendrimers are able to complex transition metals such as iron and tungsten. Copyright (C) 1996 Elsevier Science Ltd