Results of Monte Carlo simulation are often applied for quantitative X
PS or AES analysis. In this work we show that for almost homogeneous s
amples, translations and rotations of (Monte Carlo) simulated electron
trajectories lead to a substantial reduction in computation time. The
method is applied to angle-resolved XPS measurements. It is shown tha
t the distribution of a low-concentration element in the outermost 50
angstrom of a solid can be measured quantitatively.