For the first time, the effect of randomly distributed volume defects,
induced by fast neutrons, on the reflectivity spectrum of crystalline
Si has been studied. Reflectivity (R) measurements were performed at
300 K in the range 3.7-11 eV. The influence of surface preparation on
the quality of an R spectrum was checked. Proper surface treatment all
owed additional features to be revealed of the reflectivity spectrum.
It has been found that neutron irradiation tends to reduce the reflect
ivity of Si similarly as ion implantation does. Analysis of the reflec
tivity drop (DELTAR), considering the defect structure of neutron-irra
diated Si, allowed a correlation between DELTAR and the concentration
of the main defect species to be found. Precise measurements of the Si
lattice constant have shown no changes of the single-crystal structur
e after neutron irradiation. The paper proves a very high sensitivity
of optical reflection spectroscopy to the trace perturbation of the si
ngle crystalline lattice of silicon.