EVIDENCE FOR A METASTABLE STATE OF THE FUNDAMENTAL DIANION H2-

Citation
T. Sommerfeld et al., EVIDENCE FOR A METASTABLE STATE OF THE FUNDAMENTAL DIANION H2-, Physical review. A, 55(3), 1997, pp. 1903-1910
Citations number
36
Categorie Soggetti
Physics
Journal title
ISSN journal
10502947
Volume
55
Issue
3
Year of publication
1997
Pages
1903 - 1910
Database
ISI
SICI code
1050-2947(1997)55:3<1903:EFAMSO>2.0.ZU;2-#
Abstract
A resonance state with three equivalent electrons and one proton has b een identified. Large-scale calculations have been performed using the complex-rotation technique, and the results indicate that the investi gated S-4 degrees State of H2- is strongly correlated. The findings ar e rationalized by comparing with bound doubly charged anions, isoelect ronic states of the Li atom, and calculations in the infinite-dimensio n limit. In addition, the emerging picture is sustained by an analysis of the complex-rotated wave function.