ELECTRONIC-PROPERTIES OF STABLE QUASI-CRYSTALS - TOWARDS A SEMICONDUCTING QUASI-CRYSTAL

Citation
T. Klein et al., ELECTRONIC-PROPERTIES OF STABLE QUASI-CRYSTALS - TOWARDS A SEMICONDUCTING QUASI-CRYSTAL, Journal of non-crystalline solids, 156, 1993, pp. 901-904
Citations number
14
Categorie Soggetti
Material Science, Ceramics
ISSN journal
00223093
Volume
156
Year of publication
1993
Part
2
Pages
901 - 904
Database
ISI
SICI code
0022-3093(1993)156:<901:EOSQ-T>2.0.ZU;2-Q
Abstract
Anomalous transport properties are presented of a series of pure AlCuF e icosahedral phases of very high structural quality including a milli metre size single grain. The most salient feature is that all these me tallic samples present very high resistivity values close to the metal -insulator transition (MIT) using up to 10000 muOMEGA cm at 4 K in Al6 2.5Cu25Fe12.5. The resistivity at 4 K depends strongly on the structur al quality in a very peculiar way, since it increases when the structu ral defects are removed. It also varies strongly with the nominal comp osition of the sample increasing by a factor of almost 2.5 for only a 0.5% change in the composition. On the contrary, it is remarkable that the temperature dependence of the conductivity is almost independent of the composition and the structural quality. It is shown that, at lo w temperature, the temperature - and the magnetic field - dependence o f the conductivity can be analyzed with classical weak localization th eories including, however, strong electron-electron interaction simila rly to that observed in systems close to a MIT. Similar peculiar behav iours are observed by preliminary measurements in the new AlPdMn stabl e icosahedral phase.